As far as I could remember :
Season 21 : -Amy&Daniel. Probably the saddest elimination I have ever seen. And it was in Indonesia which is where I live. And also it wasn't their mistake on some level. I was so crushed.
Season 18 : -Zev&Justin.
Season 17 : -Gary&Mallory.
Season 16 : -Carol&Brandy .... LMFAO
Season 15 : -Mika&Canaan. well it wasn't really Mika, it was Canaan actually. They would have survived if it weren't for Mika's fear. Canaan seemed so crushed when FlightTime&BigEasy passed'em
Season 14 : -Kisha&Jen. They won UB later so I am happy
Season 13 : -Toni&Dallas
Season 11 : -Oswald&Danny. Although I was so upset when they cut a deal for money with Dustin&Kandice to YIELD Eric&Danielle when Mirna&Charla were happy to lend'em some.
Season 09: -Joseph&Monica. I was super upset because they got so close to make it to the final three,while The Skinny Hipsters (I forgot their names) made it (no,I didn't forget I just hate to mention'em)
Season 07: -Brian&Greg+Megan&Heidi
Season 05: -Charla&rMirna
Season 03: -Derek&Drew
Season 02: -Oswald&Danny
Season 01: -Nancy&Emily. Had they completed the Detour, UUUUGH!!!!